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Beilstein J. Org. Chem. 2013, 9, 1217–1225, doi:10.3762/bjoc.9.138
Graphical Abstract
Scheme 1: Aliphatic C–H oxidation with amidines and ketimines by 1,5-H radical shift.
Scheme 2: Aliphatic C–H oxidation with hydroperoxides.
Scheme 3: Proposed reaction mechanisms for the formation of 2a, 3a, and 4a.
Scheme 4: Proposed reaction mechanisms for the formation of 5 and 6.
Scheme 5: The reaction of secondary hydroperoxide 1o.
Scheme 6: 1,4-Dioxygenation of alkanes.
Scheme 7: Aerobic 1,4-dioxygenation of alkanes in the CuCl–NHPI catalytic system.